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EETE APRIL 2013

energy harvesting Fully recyclable organic solar cells take cellulose as an eco-friendly substrate By Julien Happich getting closer to a “solar leaf concept” Georgia Institute of Technology and Purdue University researchers have developed efficient solar cells using natural substrates derived from plants such as trees. Just as importantly, by fabricating them on cellulose nanocrystal (CNC) substrates, the solar cells can be quickly recycled in water at the end of their lifecycle. Published in the journal Scientific Reports, the researchers’ findings include organic solar cells that reach a power conversion efficiency of 2.7 percent, an unprecedented figure for cells on substrates derived from renewable raw materials. The CNC substrates on which the solar cells are fabricated are optically transparent, enabling light to pass through them before being absorbed by a very thin layer of an organic semiconductor. During the recycling process, the solar cells are simply immersed in water at room temperature. Within only minutes, the CNC substrate dissolves and the solar cell can be separated easily into its major components. Georgia Tech College of Engineering Professor Bernard Kippelen led the study and says his team’s project opens the door for a truly recyclable, sustainable and renewable solar cell technology. “The development and performance of organic substrates in solar technology continues to improve, providing engineers with a good indication of future applications,” said Kippelen, who is also the director of Georgia Tech’s Center for Organic Photonics and Electronics (COPE). “But organic solar cells must be recyclable. Otherwise we are simply solving one problem, less dependence on fossil fuels, while creating another, a technology that produces energy from renewable sources but is not disposable at the end of its lifecycle.” To date, organic solar cells have been typically fabricated on glass or plastic. Neither is easily recyclable, and petroleumbased substrates are not very eco-friendly. For instance, if cells fabricated on glass were to break during manufacturing or installation, the useless materials would be difficult to dispose of. Paper substrates are better for the environment, but have shown limited performance because of high surface roughness or porosity. However, cellulose nanomaterials made from wood are green, renewable and sustainable. The substrates have a low surface roughness of only about two nanometers. “Our next steps will be to work toward improving the power conversion efficiency over 10 percent, levels similar to solar cells fabricated on glass or petroleum-based substrates,” said Kippelen. The group plans to achieve this by optimizing the optical properties of the solar cell’s electrode. A provisional patent on the technology has been filed with the U.S. Patent Office. There’s also another positive impact of using natural products to create cellulose nanomaterials. The USA’s forest product industry projects that tens of millions of tons of them could be produced once large-scale production begins, potentially in the next five years. The research is the latest project by COPE, which studies the use and development of printed electronics. Last year the center created the first-ever completely plastic solar cell. This research was funded in part through the Center for Interface Science: Solar Electric Materials, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, by the Air Force Office of Scientific Research, by the Office of Naval Research, and the U.S. Department of Agriculture –Forest Service. Georgia Tech has created a recyclable solar cell on nanocellulose substrates made from trees. Also pictured are vials that contain the different parts of the cell after it was dissolved in water and the organic solvent. Photo courtesy: Canek Fuentes-Hernandez 16 Electronic Engineering Times Europe April 2013 www.electronics-eetimes.com


EETE APRIL 2013
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